期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 31, 页码 10016-10024出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b06291
关键词
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资金
- National Natural Science Foundation of China [21604046]
- National Young Thousand Talents Program, Shandong Provincial Natural Science Foundation, China [ZR2016XJ004]
Highly conjugated three-dimensional covalent organic frameworks (3D COFs) were constructed based on spirobifluorene cores linked via imine bonds (SP-3D-COFs) with novel interlacing conjugation systems. The crystalline structures were confirmed by powder X-ray diffraction and detailed structural simulation. A 6- or 7-fold interpenetration was formed depending on the structure of the linking units. The obtained SP-3D-COFs showed permanent porosity and high thermal stability. In application for solar cells, simple bulk doping of SP-3D-COFs to the perovskite solar cells (PSCs) substantially improved the average power conversion efficiency by 15.9% for SP-3D-COF 1 and 18.0% for SP-3D-COF 2 as compared to the reference undoped PSC, while offering excellent leakage prevention in the meantime. By aid of both experimental and computational studies, a possible photoresponsive perovskite SP-3D-COFs interaction mechanism was proposed to explain the improvement of PSC performance after SP-3D-COFs doping.
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