期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 11, 页码 3975-3980出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b12524
关键词
-
资金
- 973 project [2014CB932103]
- National Natural Science Foundation of China [91622113, 21427801]
- Natural Science Foundation of Jiangsu Province [BK20150596, BK20160029]
Molecular piezoelectrics are attracting tremendous interest because of their easy processing, light weight, low acoustical impedance, and mechanical flexibility. However, reports of molecular piezoelectrics with a piezoelectric coefficient d(33) comparable to piezoceramics such as barium titanate (BTO, 90-190 pC/N) have been scarce. Here, we present a uniaxial molecular ferroelectric, trimethylchlorome-thylammonium tribromocadmium(II) (TMCM-CdBr3), in which the halogen bonding might be a possible critical point for the stabilization of one-dimensional (1D) {CdBr3}(-) chain and further reservation of its ferroelectricity in such organic-inorganic hybrid crystalline systems. It has a large d(33) of 139 pC/N, 1 order of magnitude higher than those of most classically uniaxial ferroelectrics such as LiNbO3 (6-16 pC/N) and Rochelle salt (similar to 7 pC/N), and comparable with those of multiaxial ferroelectrics such as BTO and trimethylbromomethylammonium tribromomanganese(II) (112 pC/N). Moreover, the simple single-crystal growth and easy-to-find polar axis enable it to hold a great potential for applying in the single-crystal form. In light of the strong, specific, and directional halogen-bonding interactions, this work provides possibilities to explore new classes of molecular piezoelectrics and contribute to further developments.
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