期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 8, 页码 2769-2772出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b13512
关键词
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资金
- National Natural Science Foundation of China [21271129, 21674062, U1632117, 21704063]
- Science and Technology Commission of Shanghai Municipality [16ZR1422600, 16PJ1406600, 17YF1412100, 17JC1400700]
We report the use of helicene with an intrinsic helical molecular structure to prepare covalent organic cages via imine condensation. The organic cages revealed a [3+2]-type architecture containing a triple stranded helical structure with three helicene units arranged in a propeller-like fashion with the framework integrally twisted. Such structural chirality was retained upon dissolution in organic solvents, as indicated by a strong diastereotopy effect in proton NMR and unique Cotton effects in circular dichroism spectra. Further study on chiral adsorption showed that the chiral organic cages possess considerable enantioselectivity toward a series of aromatic racemates.
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