期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 9, 页码 3198-3201出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b13448
关键词
-
资金
- German Science Foundation (DFG) [GRK 1626]
The ligand-controlled Markovnikov and anti-Markovnikov hydrocarboxylation of styrenes with atmospheric pressure of CO2 at room temperature using dual visible-light-nickel catalysis has been developed. In the presence of neocuproine as ligand, the Markovnikov product is obtained exclusively, while employing 1,4-bis(diphenylphosphino)butane (dppb) as the ligand favors the formation of the anti-Markovnikov product. A range of functional groups and electron-poor, -neutral, as well as electron-rich styrene derivatives are tolerated by the reaction, providing the desired products in moderate to good yields. Preliminary mechanistic investigations indicate the generation of a nickel hydride (H-Ni-II) intermediate, which subsequently adds irreversibly to styrenes.
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