期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 20, 页码 6231-6234出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b03517
关键词
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资金
- National University of Singapore [CENGas R-261-508-001-646]
- Ministry of Education-Singapore [MOE AcRF Tier 1 R-279-000-472-112, R-279-000-540-114]
- Agency for Science, Technology and Research [PSF R-279-000-475-305, IRG R-279-000-510-305]
- National Natural Science Foundation of China [21771177, 21390392]
- Strategic Priority Research Program of CAS [XDB20000000]
- Key Research Program of Frontier Sciences, CAS [QYZDB-SSW-SLH019]
Metal-organic cages (MOCs) are discrete molecular assemblies formed by coordination bonds between metal nodes and organic ligands. The application of MOCs has been greatly limited due to their poor stability, especially in aqueous solutions. In this work, we thoroughly investigate the stability of several Zr-MOCs and reveal their excellent stability in aqueous solutions with acidic, neutral, and weak basic conditions. In addition, we present for the first time a process-tracing study on the postassembly modification of one MOC, ZrT-1-NHv highlighting the excellent stability and versatility of Zr-MOCs as a new type of molecular platform for various applications.
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