期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 12, 页码 4191-4194出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b12707
关键词
-
资金
- NIH [GM119374]
- University of Otago
- Faculty of Science, University of Melbourne
A nonheme iron(III) terminal methoxide complex, [Fe-III(N3PyO2Ph)(OCH3)]ClO4, was synthesized. Reaction of this complex with the triphenylmethyl radical (Ph3C center dot) leads to formation of Ph3COCH3 and the one-electron-reduced iron(II) center, as seen by UV-vis, EPR, H-1 NMR, and Mossbauer spectroscopy. These results indicate that homolytic Fe-O bond cleavage occurs together with C-O bond formation, providing a direct observation of the radical rebound process proposed for both biological and synthetic nonheme iron centers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据