期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 15, 页码 5049-5052出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b02386
关键词
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资金
- 973 Program [2015CB856600]
- NSFC/China [21625202]
- STCSM [16XD1401000]
- NSFC [21672070]
- CPSF [2016M600295]
The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3 subset of C) is presented in this study. Because of high dispersity of metallacydes within the mesoporous cavities, the stability and activity of porphyrin-containing metallacydes were obviously improved. For example, O-1(2) generation efficiency of 3 subset of C is ca. 6-fold faster than that of free metallaydes in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.
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