期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 101, 期 9, 页码 4095-4107出版社
WILEY
DOI: 10.1111/jace.15691
关键词
crystal structure; luminescence; phosphor; whitlockite-type phosphate
资金
- National Natural Science Foundation of China [11674044, 11604037, 11704054]
- Chongqing Research Program of Basic Research and Frontier Technology [CSTC2016JCYJA0113, CSTC2016JCYJA0207, CSTC2015JCYJA50005, CSTC2017jcyjAX0046]
- Chongqing Key Laboratory Improvement Plan (Chongqing Key Laboratory of Photoelectronic Information Sensing and Transmitting Technology) [cstc2014pt-sy40001]
- University Innovation Team Construction Plan Funding Project of Chongqing (Architecture and core technologies of smart medical system) [CXTDG201602009]
- China-Poland Intergovernmental Science and Technology Cooperation Program [2015[170]/36-13]
A series of novel red-emitting Ca8ZnLa1-xEux(PO4)(7) phosphors were successfully synthesized using the high-temperature solid-state reaction method. The crystal structure, photoluminescence spectra, thermal stability, and quantum efficiency of the phosphors were investigated as a function of Eu3+ concentration. Detailed analysis of their structural properties revealed that all the phosphors could be assigned as whitlockite-type -Ca-3(PO4)(2) structures. Both the PL emission spectra and decay curves suggest that emission intensity is largely dependent on Eu3+ concentration, with no quenching as the Eu3+ concentration approaches 100%. A dominant red emission band centered at 611nm indicates that Eu3+ occupies a low symmetry sites within the Ca8ZnLa(PO4)(7) host lattice, which was confirm by Judd-Ofelt theory. Ca8ZnLa1-xEux(PO4)(7) phosphors exhibited good color coordinates (0.6516, 0.3480), high color purity (similar to 96.3%), and high quantum efficiency (similar to 78%). Temperature-dependent emission spectra showed that the phosphors possessed good thermal stability. A white light-emitting diode (LED) device were fabricated by integrating a mixture of obtained phosphors, commercial green-emitting and blue-emitting phosphors into a near-ultraviolet LED chip. The fabricated white LED device emits glaring white light with high color rendering index (83.9) and proper correlated color temperature (5570K). These results demonstrate that the Ca8ZnLa1-xEux(PO4)(7) phosphors are a promising candidate for solid-state lighting.
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