期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 258, 期 -, 页码 841-844出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2017.12.011
关键词
Pyrazole; SBUs; Topology; ECL
资金
- Fundamental Research Funds for the Central Universities [3207045420]
- Key Research Project of Natural Science from Provincial Bureau of Education, Anhui, China [KJ2017A572]
- Program of College Students Innovation of Laboratory Construction [2016ckjh116]
- Jiangsu Ainaji Neoenergy Science &Technology Co., Ltd [8507040091]
Two 3D microporous MOFs, [Zn-4(mu(4)-O)(mu(4)-pzca)(3)](n) (1) and Zn-2(Pzca)(2)(4,4'-biPY)]2H(2)O}(n) (2) (H(2)pzca=1H-pyrazole-4-carboxylic acid) were synthesized. The X-ray data reveals that the 1 contains Zn-4(mu(4)-O)(CO2)(6)] and [Zn-4(mu(4)-O)(N-2)(6)] SBUs, the 2 contains Zn2N6O2 SBUs. Furthermore, MOFs 1 and 2 have a same topology pcu net. Interestingly MOF 1 exhibits good ECL (electrochemiluminescence) behavior.
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