期刊
JOURNAL OF POWER SOURCES
卷 397, 期 -, 页码 162-169出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.07.019
关键词
Surface amorphous structure; TiO2 nanoparticles; Graphene; Hybrid materials; Lithium-ion batteries
资金
- National Natural Science Foundation of China [51671092, 51631004]
- ChangBai Mountain Scholars Program
- Natural Science Foundation of Jilin Province [20160101315JC]
- Program for JLU Science and Technology Innovative Research Team [2017TD-09]
- Fundamental Research Funds for the Central Universities
One demanding challenge in the development of high-power batteries is to achieve superior rate and cycling performances. Here, we report a two-step method to fabricate a hybrid material of surface-amorphized TiO2/reduced graphene oxide (SA- TiO2/RGO), which exhibits superior electrochemical properties as an anode material in lithium-ion batteries, high rate property of 135.6 mAh g(-1) at a current density of 10 Ag-1 and cycling stability of 98 mAh g(-1) after 2000 cycles at 5 Ag-1. These excellent performances originate from the unique three-dimensional integrated structure of SA-TiO2/RGO, which provides: (i) a conductive substrate of RGO; (ii) higher conductivity of SA-TiO2 relative to crystallized-TiO2; (iii) ultra-small SA-TiO2 nanoparticles; and (iv) excellent contact between SA-TiO2 and RGO through C-O-Ti bonds.
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