期刊
JOURNAL OF POWER SOURCES
卷 387, 期 -, 页码 64-71出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.03.047
关键词
Zinc oxide nanoflower; Micro-nano secondary structure; Dopamine; Carbon coating; Anode material
资金
- National Natural Science Foundation of China [51673117, 51574166]
- National High-tech RD Program (863) [2015AA03A204]
- Science and Technology Innovation Commission of Shenzhen [JCYJ20150529164656097, JCYJ20150625102750478, JSGG20160226201833790, JCYJ20160520163535684, JCYJ20160422144936457]
The rational structure design and strong interfacial bonding are crucially desired for high performance zinc oxide (ZnO)/carbon composite electrodes. In this context, micro-nano secondary structure design and strong dopamine coating strategies are adopted for the fabrication of flower-like ZnO/carbon (ZnO@C nanoflowers) composite electrodes. The results show the ZnO@C nanoflowers (2-6 mu m) are assembled by hierarchical ZnO nanosheets similar to 27 nm) and continuous carbon framework. The micro-nano secondary architecture can facilitate the penetration of electrolyte, shorten lithium ions diffusion length, and hinder the aggregation of the nanosheets. Moreover, the strong chemical interaction between ZnO and coating carbon layer via C-Zn bond improves structure stability as well as the electronic conductivity. As a synergistic result, when evaluated as lithium ion batteries (LIBs) anode, the ZnO@C nanoflower electrodes show high reversible capacity of ca. 1200 mA h g(-1) at 0.1 A g(-1) after 80 cycles. As well as good long-cycling stability (638 and 420 mA h g(-1) at 1 and 5 A g(-1) after 500 cycles, respectively) and excellent rate capability. Therefore, this rational design of ZnO@C nanoflowers electrode is a promising anode for high-performance LIBs.
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