Performance of integrated bioelectrochemical membrane reactor: Energy recovery, pollutant removal and membrane fouling alleviation

A novel hybrid bioelectrochemical membrane reactor with integrated microfiltration membrane as the separator between electrodes is developed for domestic wastewater treatment. After accumulation of biofilm, the organic pollutants are mainly degraded in anodic compartment, and microfiltration membrane blocks the adverse leakage of dissolved oxygen from aerated cathodic compartment. The maximum system power output is restricted by gas-water ratio following a Monod-like relationship. Within the tested gas-water ratios ranging from 0.6 to 42.9, the half-saturation constant (K-Q) is 5.9 +/- 0.9 with a theoretic maximum power density of 20.4 +/- 1.0 W m(-3). Energy balance analysis indicates an appropriate gas-water ratio regulation (from 2.3 to 28.6) for cathodic compartment is necessary to obtain positive energy output for the system. A maximum net electricity output is 9.09 x 10(-3) kWh m(-3) with gas-water ratio of 17.1. Notably, the system achieves the chemical oxygen demand removal of 98.3 +/- 0.3%, ammonia nitrogen removal of 99.6 +/- 0.1%, and total nitrogen removal of 80.0 +/- 0.9%. This work verifies an effective integration of microfiltration membrane into bioelectrochemical system as separator for high-quality effluent and provides an insight into the operation and regulation of biocathode system for effective electrical energy output.