期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 122, 期 17, 页码 4748-4757出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.8b01819
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资金
- University of Saskatchewan
- Beijing Institute of Technology through IFPRG
- Government of Canada through the Natural Sciences and Engineering Research Council of Canada [RGPIN 2016-06197]
- Mitacs
Templated (T) and nontemplated (NT) cross-linked materials containing beta-cyclodextrin (beta-CD) and epichlorohydrin (EPH) were prepared at variable beta-CD-EPH ratios (1:15, 1:20, and 1:25) in the presence and absence of a molecular template (toluene). The structural characterization of the materials was carried out using spectroscopy (Fourier transform infrared, solids C-13 NMR, and scanning electron microscopy) and thermogravimetric analysis. The adsorption properties were studied with phenol-based adsorbates (2,4,6-trinitrophenol (TNP) and p-nitrophenol (PNP)) at equilibrium and dynamic conditions. The monolayer adsorption capacity (Q(m)) varied for the T-polymer/TNP systems (Q(m) = 0.10-0.95 mmol/g) and NT-polymer/TNP systems (Q(m) = 0.23-0.83 mmol/g). The range of Q(m) values for the T-polymer/PNP systems (0.26-0.62 mmol/g) exceeded that of the NT-polymer/PNP systems (0.23-0.40 mmol/g). The kinetic uptake profiles for the polymers and phenolphthalein were reliably described by the pseudo-first-order model. The beta-CD inclusion site accessibility for the polymers varied from 15 to 20%, according to the level of cross-linking, where the accessibility of the T-polymers exceeded that of the NT-polymers. The structural characterization and phenol adsorption properties provide complementary support for the role of tunable polymer morphology in adsorption processes. The role of two-site binding was demonstrated for linear and globular polymer materials according to their unique adsorption properties with phenols of variable size and hydrophile-lipophile character.
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