期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 364, 期 -, 页码 516-523出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2018.06.035
关键词
Nano-TiO2-SO3H; Photo-catalysis; Solid acid; Oxidation of alcohols; Blue LED
资金
- Faculty of Chemistry of Semnan University
Nano photo-catalyst 'TiO2-P25-SO3H' has been synthesized for the first time as a covalently grafted solid acid and used for the oxidation of different aromatic alcohols to the corresponding carbonyl compounds under visible light irradiation (blue LED, lambda > 420 nm). This new and efficient nano photo-catalyst has selectively converted primary aromatic alcohols to the corresponding aldehydes in the presence of nitrobenzene as available industrial oxidant with excellent yields. This new powerful nano photo-catalyst provides a green and mild approach for photo-oxidation of alcohols.
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