期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 873, 期 -, 页码 8-14出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2018.07.022
关键词
Transfer hydrogenation; Nickel; N-heterocyclic carbene; Catalysis
资金
- Stockton University
Three new nickel complexes featuring primary amido-functionalized N-heterocyclic carbene ligands have been synthesized and characterized using NMR spectroscopy, combustion analysis, and, in one case, single crystal x-ray diffraction. Each complex serves as a pre-catalyst for base-free transfer hydrogenation of aryl ketones in air using 2-propanol or 2-butanol as the solvent and hydrogen donor. Furthermore, in methanol-d(4) solutions of the nickel complexes, hydrogen-deuterium exchange is observed on the ligands at moderate temperatures. These nickel complexes represent rare examples of transfer hydrogenation catalysts that operate under base-free and aerobic conditions. (C) 2018 Elsevier B.V. All rights reserved.
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