期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 867, 期 -, 页码 342-346出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2017.11.014
关键词
Rhodacarboranes; 16-Electron complexes; Synthesis; X-ray structure
资金
- Russian Foundation for Basic Research [16-53-53079]
- National Natural Science Foundation of China [21611130027]
16-Electron half-sandwich rhodium complexes containing carborane ligands of two different sigma- and pi-types 3,3-mu-(1',2'-C2B10H10-1',2'-S-2-)-4-L-3,1,2-RhC2B9H10 (L = SMe2, NMe3, NMe2CH2Ph) were synthesized for the first time. The solid state structures of 3-(COD)-4-PhCH2Me2N-3,1,2-RhC2B9H10 and 3,3-mu-(1',2'-C2H10H10-1',2'-S-2)-4-Me3N-3,1,2-RhC2B9H10 were determined by single crystal X-ray diffraction. (C) 2017 Elsevier B.V. All rights reserved.
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