期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 18, 页码 11145-11153出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01745
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资金
- SERB, New-Delhi [EMR/2016/006358]
- CSIR [02(0226)15/EMR-II]
- CSIR, New-Delhi
A chemoselective formation of C-N bond catalyzed by iodine has been developed using heterocyclic thiols and thiones. The reaction occurs at the nitrogen center over the sulfur, leading to the amination against the traditional sulfenylation. A wide variety of allylic and benzylic alcohols serve as coupling partners. This method showed a good tolerance toward 1H-tetrazole-5-thiol, 5-methyl-1,3,4-thiadiazole-2-thiol, benzo[d]thiazole-2(3H)-thione, and benzo[d]oxazole-2(3H)-thione derivatives.
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