期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 16, 页码 9422-9429出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01030
关键词
-
资金
- National Natural Science Foundation of China [21672138, 21542005, 21272152]
Fluoroalkylated quinoxlines with various groups were efficiently synthesized via a one-pot tandem Michael addition/azidation/cydoamination process. Under the mild and metal-free conditions, a bis-imine intermediate (4a) was detected and isolated for the first time. KI played a crucial role in this reaction. The mechanism was described.
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