4.7 Article

Phenyliodine(III) Bis(trifluoroacetate) (PIFA)-Mediated Synthesis of Aryl Sulfides in Water

期刊

JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 14, 页码 7553-7558

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00435

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资金

  1. Natural Science Foundation of China [21502094]
  2. Natural Science Key Project of the Jiangsu Higher Education Institutions [17KJA220003]
  3. Natural Science Foundation of Jiangsu Province [BK20140969]
  4. Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
  5. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  6. advanced analysis and testing center of Nanjing Forestry University

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An environmentally benign method for the synthesis of aryl sulfides in water under mild conditions has been realized, in which arenes are coupled with equal stoichiometry of allyl sulfides. This arylthiolation is enabled by the presence of the Lipshutz surfactant, TPGS-750-M, using water as the recyclable reaction medium.

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