期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 15, 页码 7751-7761出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00648
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资金
- CNRS (Centre National de la Recherche Scientifique, France)
- International Centre for Frontier Research in Chemistry (IcFRC)
- Indo-French Centre for the Promotion of Advanced Research (IFCPAR)
- University of Strasbourg Institute for Advanced Study (USIAS)
The trapping of racemic polar carbometallic species with (-)-menthyl (Ss)-p-toluenesulfinate (Andersen's reagent) typically proceeds with a very low level of resolution. In this paper, we describe a strategy that allows access to highly atropoenriched and functionalizable biphenyls by means of Andersen's reagent under kinetic resolution conditions. In particular, useful enantiopure 2-iodobiphenyls could be obtained and were employed in a challenging hypervalent iodine-catalyzed oxidation
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