期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 6, 页码 3078-3089出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00306
关键词
-
资金
- JSPS [16K05769]
- Grants-in-Aid for Scientific Research [16K05769, 16K17851] Funding Source: KAKEN
A highly diastereoselective alpha-allylation of selenolactams with allyl halides is reported. DFT analyses and experimental observations suggested that this reaction proceeds via a Se-allylation of the eneselenolates of the lactams followed by a seleno-Claisen rearrangement. The thus obtained products could be efficiently transformed into polycyclic amines using a previously developed sequential addition of organometallic reagents and ring-closing metathesis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据