期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 18, 页码 11323-11326出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01544
关键词
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资金
- University of California, Los Angeles
- National Science Foundation [CBET1605877]
- Packard Foundation
- Foote Family
- Chemistry-Biology Interface training program [5T32GM008496-20]
- NSF [CHE-1048804]
- NIH NCRR [S10RR025631]
An operationally simple protocol for the conversion of geranyl acetate to 8-hydroxygeraniol is reported. The convenient two-step procedure relies on an efficient, chemo- and regioselective SeO2-promoted oxidation, followed by straightforward deacetylation. This facile means to prepare 8-hydroxygeraniol is expected to enable biosynthetic studies pertaining to thousands of monoterpene indole alkaloids.
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