期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 8, 页码 4657-4664出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b00427
关键词
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资金
- Scientific Research Fund of Hunan Provincial Education Department [16A087]
- National Natural Science Foundation of China [21602056]
A new FeCl2- and DTBP (di-tert-butyl peroxide)-promoted oxidative ring-opening and cyclization of methylenecyclopropanes with aldehydes for the synthesis of 2-acyl-3,4-dihydronaphthalenes is presented. This oxidative cyclization reaction proceeds via a radical addition, ring-opening, and cyclization sequence facilitated by a Lewis acid, and it offers a practical and straightforward route for the oxidative cyclization of methylenecyclopropanes with an aromatic carbon and a C(sp(2))-H bond by simultaneously forming two new carbon carbon bonds.
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