4.8 Article

Aerobic oxidative C-H/C-H coupling of azaaromatics with indoles and pyrroles in the presence of TiO2 as a photocatalyst

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GREEN CHEMISTRY
卷 17, 期 8, 页码 4401-4410

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00753d

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  1. Russian Science Foundation [14-13-01177]

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In this paper we wish to report a highly selective and benign method for the double C-H/C-H coupling of azaaromatics with indoles or pyrrole in the presence of air oxygen/TiO2, as an effective photocatalytic oxidative system. It has been shown that this versatile approach can be applied for direct C-H functionalisation of a variety of azaaromatic systems, such as mono-, di- and triazines, substituted and unsubstituted azines and their benzo-annelated analogues.

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