期刊
GREEN CHEMISTRY
卷 17, 期 4, 页码 2480-2486出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc02408g
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资金
- university grant commission, India
- Green Technology Centre of Institute of Chemical Technology (ICT), Mumbai, India
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
This work reports a copper-catalyzed novel protocol for the tandem synthesis of 2-benzimidazolone derivatives from dimethyl carbonate (DMC) and various 2-nitroanilines by using polymethylhydrosiloxane (PMHS) as an inexpensive, stable and environmentally benign reducing agent. This methodology is applicable for the preparation of a broad range of biologically active 2-benzimidazolone derivatives with a good scope in good to excellent yields.
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