期刊
GREEN CHEMISTRY
卷 17, 期 7, 页码 4068-4072出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00403a
关键词
-
资金
- SERB [SR/S1/OC-38/2011]
- DST-FIST program (HRMS facility), New Delhi
- CSIR
A novel, efficient and unprecedented green protocol for the formation of C-S bonds has been developed under metal-free conditions. This protocol involves the synthesis of aryl sulfides through the cross-dehydrogenative coupling of readily available aryl thiols with electron-rich species under solvent-free conditions and the corresponding aryl sulfides are obtained in high to quantitative yields. A catalytic amount of inexpensive and non-toxic iodine drives the reaction and no exclusion of air and expensive ligands is required.
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