期刊
GREEN CHEMISTRY
卷 17, 期 11, 页码 4908-4912出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00186b
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资金
- European Commission (SuBiCat Initial Training Network, Call FP7-PEOPLE-ITN) [607044]
- Cluster of Excellence Tailor Made Fuels from Biomass (TMFB) - Excellent Initiative of the German federal and state governments
- international training network SubiCat
- NRW Graduate School BrenaRo
- German Academic Exchange Service (DAAD)
A base-catalysed transformation and cleavage of lignin beta-O-4 model compounds in dimethyl carbonate is reported. The reaction system consists of readily available bases and inexpensive dimethyl carbonate as a solvent and reagent, affording methoxy benzene or 2-aryloxyvinyl benzene derivatives in good to very good yields. The applicability of the system for the bond cleavage in an organosolv lignin sample was demonstrated.
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