期刊
GREEN CHEMISTRY
卷 17, 期 6, 页码 3508-3514出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5gc00438a
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资金
- Bu-Ali Sina University Research Council
- Center of Excellence in Development of Environmentally Friendly Methods for Chemical Synthesis (CEDEFMCS)
Syntheses of two different types of disulfonamide and sulfonamide derivatives of N,N-dimethyl-1,4-benzenediamine were carried out by the electrochemical oxidation of 4-nitroso-N,N-dimethylaniline in the presence of arylsulfinic acids as nucleophiles and by the chemical reaction of 4-nitroso-N,N-dimethylaniline with arylsulfinic acids. The electrochemical synthesis was carried out in aqueous ethanol at pH 7.0 and gave the pure N,N-diarylsulfonyl derivatives in 55-76% yield. The chemical synthesis, carried out in water at pH 2.0, provided the pure N-arylsulfonyl-3-arylsulfonyl derivatives in 75-85% yield.
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