期刊
GREEN CHEMISTRY
卷 17, 期 2, 页码 812-816出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc01299b
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资金
- National Natural Science Foundation of China [21173089, 21373093]
- Fundamental Research Funds for the Central Universities of China [2014ZZGH019]
In the absence of an external reductant, C3-cycloalkylated indole could be synthesized through reductive alkylation of indole with cyclic ketone using a sulfonyl-functionalized Bronsted acid ionic liquid as a catalyst. Water generated in the initial stage of the reaction played a key role in rendering the reductive coupling possible. The reaction proceeds most likely in a radical way.
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