期刊
GREEN CHEMISTRY
卷 17, 期 2, 页码 837-841出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc01990c
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资金
- University Nice Sophia Antipolis
- CNRS
- ANR program CD2I (Nanocausys project) [12-CDII-0010-02]
We describe herein an efficient and particularly sustainable catalytic system for the intramolecular hydroalkoxylation of double bonds. A heterogeneous catalyst based on the impregnation of benign metals such as iron and bismuth on montmorillonite was used for a highly atom-economic transformation in DMC, a non-VOC solvent. The transformation allowed the formation of a large range of cyclic ethers from the corresponding unsaturated alcohols and the catalyst could be recycled several times.
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