期刊
GREEN CHEMISTRY
卷 17, 期 2, 页码 817-820出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc01790k
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资金
- National Nature Science Foundation of China (NSFC) [21173214]
A new vanadoperiodate [HIV9O28](3-) has been synthesized by a simple, one-pot stoichiometric reaction of HIO4 center dot 2H(2)O with NaVO3 in aqueous solution and then isolated as [C8H17N(CH3)(3)](3)HIV9O28 by cation exchange. We have found that [C8H17N(CH3)(3)](3)HIV9O28 shows high catalytic activity in the oxidation of refractory sulfur-containing compounds to their corresponding sulfones using molecular oxygen as oxidant under mild reaction conditions.
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