期刊
JOURNAL OF NATURAL PRODUCTS
卷 81, 期 8, 页码 1899-1904出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jnatprod.8b00527
关键词
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资金
- Air Force Office of Scientific Research through Basic Research Initiative grant [AFOSR FA9550-16-1-0113]
- Direccion General de Asuntos del Personal Academico UNAM [IN2013416]
- SERB, DST, Government of India
While most scorpion venom components identified in the past are peptidic or proteinic in nature, we report here a new alkaloid isolated from the venom of the Mexican scorpion Megacormus gertschi. Nuclear magnetic resonance and mass spectrometric investigations elucidate the structure of the alkaloid as (Z)-N-(2-(1H-imidazol-4-yl)ethyl)-3-(4-hydroxy-3-methoxyphenyl)-2-methoxyacrylamide (1). A chemical method of synthesizing this alkaloid is also described. Although abundant in venom, the above alkaloid was not found to have insecticidal activity. Structural analysis suggests that this venom alkaloid might be of potential interest for evaluating its medicinal effect.
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