期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 18, 期 6, 页码 4255-4263出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2018.15194
关键词
Polyacrylonitrile; Graphene; Electrospinning; Yarns; Properties
类别
资金
- Nantong Science and Technology Program Project [GY12016025]
- Priority Academic Program Development of the Jiangsu Higher Education Institutions [KYCX17-1985]
- Postgraduate Research and Practice Innovation Program of Jiangsu Province [KYCX17-1985]
In this paper, polyacrylonitrile/graphene composite nanofiber filaments were manufactured continuously by a homemade eight-needle electrospinning device with an auxiliary electrode. The polyacrylonitrile/graphene composite nanofiber yarns were obtained continuously by plying and twisting the composite nanofiber filaments. The structures and properties of the composite nanofiber filaments with different GP mass fractions and yarns were investigated. The results demonstrated that the maximum alignment degree of the composite nanofibers along the filament axis could reach 74.3% with 1%, and the alignment degree decreased with increasing graphene mass fraction. The diameters of the composite nanofibers were considerably smaller than those of the pure polyacrylonitrile nanofiber, and the minimum diameter was 156 nm for 1%. The conductivity of the composite nanofiber filaments was significantly enhanced by seven orders of magnitude compared with that of the pure polyacrylonitrile nanofiber filament, and the maximum value was 3.73x10(-7) S/cm for 1.5%. Due to graphene agglomeration, the conductivity decreased when the mass fraction was more than 1.5%. The different number of filaments and twists were examined in detail to improve the poor mechanical properties of the nanofiber filaments. With an increase in twists, the breaking stress and strain increased initially and later decreased, and the maximum breaking stress and strain were 16.54 MPa and 26.42%, respectively. This study demonstrates the possibility of continuously and stably manufacturing polyacrylonitrile/graphene composite nanofiber yarns.
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