期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1166, 期 -, 页码 79-90出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2018.04.025
关键词
Schiff bases; Titanium(IV) complexes; Aroylhydrazine; Nicotinic acid hydrazide; Dibasic tridentate ligands; Computational study; Octahedral geometry; Anti-microbial and antioxidant properties
The titanium(IV) complexes of Schiff bases derived from aroylhydrazine e.g. benzoylhydrazine, salicyloylhydrazine, nicotinic acid hydrazide with aldehyde or ketone are reported and characterized based on UV-vis spectroscopy, (Infra-red) IR spectra, H-1 NMR spectra, mass spectra, magnetic susceptibility and molar conductance measurements. Complexes are found to possess 1:2 (metal:ligand) stoichiometry. The prepared ligands were act as dibasic tridentate ligands. On the basis of experimental evidences octahedral geometry has been proposed for prepared complexes. Geometry was confirmed by the optimized structure obtained from computational study. The synthesized ligands, in comparison to their titanium(IV) complexes, were also screened for their microbial and antioxidant properties. (C) 2018 Elsevier B.V. All rights reserved.
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