期刊
JOURNAL OF MEMBRANE SCIENCE
卷 548, 期 -, 页码 526-539出版社
ELSEVIER
DOI: 10.1016/j.memsci.2017.11.033
关键词
LaCoO3-delta; Kinetic demixing/decomposition; Oxygen potential gradient; Oxygen membrane
资金
- Danish Council for Strategic Research/Innovationsfonden [11-116387]
- State Key Laboratory of Powder Metallurgy Foundation, Central South University, Changsha, China
A composition-and temperature-dependent mobility database of all ionic species in the LaCoO3-delta phase was developed and combined with a La-Co-O thermodynamic database to simulate kinetic demixing and partial decomposition in LaCoO3-delta oxygen membranes operated under a 0.0001/0.21 bar oxygen partial pressure difference at 1073 K for 1 year. Formation of La2O3, Co3O4 and CoO phases across the membrane is predicted. The kinetic demixing process can be divided into two stages, namely, establishment of the oxygen potential gradient (fast) and demixing of the cations (slow); the former is controlled by the mobility of oxygen ions, and the latter is determined by the higher mobility of Co ions as compared to the La ion in the ABO(3)-type perovskite. A drift motion of both oxide surfaces towards the high PO2 side occurs with the movement of cations.
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