期刊
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
卷 29, 期 13, 页码 11613-11626出版社
SPRINGER
DOI: 10.1007/s10854-018-9259-x
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类别
资金
- CONACYT [CB-256795-2016, CB-2014-237049, INFRA-2015-252753, PN-2015-01-487, NRF-2016-278729, 386267]
- SEP [PROFOCIE- 2014-19-MSU0011T-1, PRODEP-103.5/15/14156]
- UANL (PAICYT)
- FIC-UANL [PAIFIC 2015-5]
- Swedish Research Council Formas
Earth-abundant metal sulfides (for example, FeS2, CuS, and NiS2) are promising materials to be used as photocatalysts due to their suitable electronic and optical properties. In this work, we present a fast and low-cost hydrothermal method to synthesize these materials. They are integrally characterized and evaluated as photocatalysts for the H-2 evolution reaction and the degradation of indigo carmine (IC). FeS2 exhibits the highest photocatalytic efficiency (32 A mu mol g(-1) h(-1) of H-2 evolution and 88% of indigo carmine degradation) under visible light, and this activity is attributed to a larger crystallite size, smaller particle size, and lower recombination, compared to CuS and NiS2. Moreover, three different sacrificial reagents are studied for the H-2 evolution reaction, including Na2S/Na2SO3, EDTA, and ethanol. Na2S/Na2SO3 shows the highest enhancement in the activity, increasing the rate of H-2 production more than 15 times. This behavior is related to the lower oxidation potential of Na2S/Na2SO3. Moreover, we evaluate the activity of the materials for the electrochemical hydrogen evolution reaction (HER). In summary, this work provides valuable information for effective applications of these earth-abundant metal sulfides for energy and environmental photocatalytic processes.
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