期刊
JOURNAL OF MATERIALS SCIENCE
卷 53, 期 17, 页码 12016-12029出版社
SPRINGER
DOI: 10.1007/s10853-018-2476-0
关键词
-
资金
- National Natural Science Foundation of China [61604110]
- Key Technology R&D Program of Hubei Province [2015BCA253]
- China Postdoctoral Science Foundation [2015M572210, 2016M602376]
- Open Foundation of The State Key Laboratory of Refractories and Metallurgy [2014QN17]
- Natural Science Foundation of Hubei Provincial China [2017CFB291]
- Department of Education Science Research Program of Hubei Province [Q20161110]
- Open Foundation of Key Laboratory of Green Chemical Process (Wuhan Institute of Technology), Ministry of Education [NRGCT201503]
- Training Programs of Innovation and Entrepreneurship for Undergraduates of Province [201510488022]
The porous and water-stable polyoxometalates-based Zr-MOFs PW12@UiO-NH2 was proposed for photocatalytic H-2 evolution and degradation pollutants via adopting Keggin-type polyoxometalates (POMs) into UiO-66-NH2 through a facile one-step solvothermal method. Systematically characterizations were carried out to confirm the encapsulation of Keggin-type PW12 within the cavities of porous UiO-66-NH2 without modifying its fundamental framework. Benifiting from the integration of Keggin-type PW12 units with redox activity and porous UiO-66-NH2, the results showed that enhanced photocatalytic H-2 evolution performance and RhB degradation activity for PW12@UiO-NH2 were realized compared with pristine UiO-66-NH2 under visible-light irradiation. The significant improvement of photocurrent density under a monochromatic light irradiation implied the faciliated separation procedure of photo-generated charge carriers with the incorporation of Keggin-type PW12 units. Hence, our findings reveal a novel topology POM-based MOFs which paves a way for environmental and energy applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据