期刊
JOURNAL OF LUMINESCENCE
卷 194, 期 -, 页码 778-784出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jlumin.2017.09.050
关键词
Upconversion; Sensitization; Energy transfer; Er3+ ions; Crystalline silicon solar cells
类别
资金
- Advanced Low Carbon Technology Research and Development Program (ALCA), Japan Science and Technology Agency
We investigated three pathways of energy transfer between Ni2+ sensitizers and Er3+ emitters in broadband-sensitive La(Ga0.5Sc0.5)O-3: Er,Ni,Nb upconverters emitting at 0.98 mu m for crystalline silicon solar cells. The results were interpreted based on simplified models of the emission mechanisms. A high efficiency close to unity was successfully achieved for the Ni2+-> Er3+ (I-4(13/ 2)) energy transfer, meaning efficient sensitization. Energy dissipation caused by the Er3+ (I-4(13/2))-> Ni2+ back transfer was minor. However, detrimental impact of another back transfer from the initial state of the upconversion emission Er3+ (I-4(11/2)) competed against improvements in the absorbance and energy transfer upconversion with increasing Ni2+ and Er3+ concentrations, which limited the upconversion efficiency. Precise tuning of the Ni2+ absorption band to suppress the second back transfer can improve the upconversion performance.
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