期刊
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
卷 25, 期 6, 页码 658-665出版社
SPRINGER
DOI: 10.1007/s42243-018-0088-1
关键词
High-entropy bulk metallic glass; Fracture mechanism; Crystallization; Avrami exponent; Glass-transition activation energy
资金
- National Key Research and Development Project of China [2016YFB0300500]
- MOST 973 Program [2015CB856800]
- NSF of China [51571079]
- Fundamental Research Funds for the Central Universities in China [JZ2016HGPB0671]
The mechanical properties, thermodynamic features and their correlation were studied for La-Ce-Ni-Cu-Al high-entropy bulk metallic glasses (HE-BMGs). Compressive testing indicated that the HE-BMGs are ductile on a microscopic scale but brittle on a macroscopic scale, because of the low fragility index m of the HE-BMGs. In the non-isothermal process, the activation energies for glass transition for these HE-BMGs are the lowest of the known HE-BMGs. Large values of the Avrami exponent n imply that the crystallization process proceeded through three-dimensional growth and with an increasing nucleation rate. The activation energy for glass transition (E (g)) is almost proportional to the HE-BMG fracture strength, because a higher E (g) is required to dislodge the molecules from the glassy configuration for the HE-BMGs with a high strength. The findings provide unambiguous evidence for the correlation between the mechanical and thermodynamic properties.
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