期刊
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
卷 2, 期 2, 页码 907-913出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2014.02.005
关键词
Fe3O4@C nanoparticles; Nanoadsorbent; Hydrothermal method; Methylene blue; Regeneration
资金
- Science & Technology Department of Sichuan Province [2013FZ0060]
- China Natural Science Foundation [21307101, 21301015]
- China Ministry of Science and Technology (973) [2011CB933402]
- National Training Programs of Innovation and Entrepreneurship [201310656006]
Magnetic Fe3O4@C nanoparticles (NPs) were fabricated by hydrothermal synthesis for the adsorption of methylene blue (MB). Fe3O4@C NPs were prepared from FeCl2, FeCl3 and glucose after hydrothermal treatment at 160 degrees C for 6 h. After characterization by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and infrared spectrometer, the adsorption behaviors of MB on Fe3O4@C NPs were investigated. The results indicated that Fe3O4@C NPs adsorbed MB effectively with a large capacity of 117 mg/g. The adsorption isotherm was described by Temkin model. The adsorption reached the equilibrium within 3 h and the kinetics followed pseudo-second-order model. The increase of ionic strength inhibited the adsorption, and the decrease of pH led to the dramatic decrease in adsorption capacity. The adsorption was endothermal, thus higher temperature was preferred. The magnetic separation after adsorption was easily achieved and Fe3O4@C NPs could be regenerated by washing with HCl aqueous solution. (C) 2014 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据