期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 28, 期 3, 页码 1158-1170出版社
SPRINGER
DOI: 10.1007/s10904-018-0785-z
关键词
Heterogeneous; Naphthyl-azo; Aminopolystyrene; Iron anchored; Toluene; Hydrogen peroxide
资金
- Department of Science and Technology, West Bengal (DST-WB) [811(sanc.)/ST/P/ST/4G-8/2014]
- NFOBC for UGC, New Delhi
- SERB-NPDF, DST, New Delhi, India [PDF/2017/000478]
- Department of Science and Technology (DST)
- University Grant Commission (UGC) New Delhi, India
A new and interesting heterogeneous iron-anchored naphthyl-azo catalyst (PS-Fe-NAPA) has been designed using aminopolystyrene and 2-nitrosonaphthol followed by loading iron in the naphthyl-azo complex. The prepared polymer supported material has been well characterized by FE-SEM, EDAX, TGA analysis, UV-Vis, FTIR, AAS, and elemental analysis. Iron-anchored naphthyl-azo complex exhibited excellent catalytic activity for the selective oxidation of toluene and substituted toluenes containing inactive benzylic C-H bonds in presence of mild oxidant hydrogen peroxide. Additionally, PS-Fe-NAPA complex is highly recyclable up-to six times without loss of its significant catalytic efficiency.
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