期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 364, 期 -, 页码 791-799出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.07.023
关键词
Palm oil mill effluent; Fenton oxidation; Carbon balance; Nitrogen balance; Intermediate products
An in-depth study on degradation behavior of palm oil mill effluent (POME) in Fenton oxidation was accomplished with complete carbon and nitrogen balances. Experiments were conducted for real POME with a pH range of 2-5. POME contained high COD (50,000 mg/L), nitrogen (520 mg/L) and phosphorous (510 mg/L). Carboxylic acids and phenol covered 88% of organic carbons while ammonia, NO2- and NO3- contributed for 73% of nitrogen. Most of carboxylic acids and phenol were decomposed forming easily-biodegradable formic, phthalic and acetic acids, and further decomposed to carbonate and gaseous carbon dioxide. Part of carbon in liquid phase in POME transferred to solid phase by oligomerization of aromatic compounds. Ammonia was oxidized to NO2-, NO3- and gaseous N-2 while, acetamide degradation led to ammonia formation. 99.9% of phosphorus was removed. Increasing 14202 concentration elevated organic reduction and the highest TOC reduction of 91% was obtained at TOC:H2O2:Fe2+ molar ratio of 1:3.7:0.6 within 90-180 min which is extremely faster over the available biological treatments. Under the reaction conditions used in this study, Fenton oxidation at pH 3 showed the best result in terms of TOC reduction. Outcomes of this study will provide a platform for advanced oxidation processes and POME treatment.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据