期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 210, 期 -, 页码 88-93出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2018.03.008
关键词
Diels-Alder cycloaddition; Organofluorine compounds; Polycyclic aromatic hydrocarbons
资金
- Russian Foundation for Basic Research [16-33-00944]
1,1-Difluoronaphthalen-2(1H)-ones were used as building blocks for synthesis of functionalized fluorinated tetraphenones via Diels-Alder reaction. Two effective methods of tetraphenone reductive aromatization were proposed. Fully aromatic stable fluorinated tetraphene derivative with high solubility and HOMO-LUMO gap of 3.08 eV was obtained.
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