期刊
JOURNAL OF ENVIRONMENTAL MANAGEMENT
卷 211, 期 -, 页码 53-62出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2018.01.014
关键词
Ball milling process; Magnetite nanoparticles; Heterogeneous Fenton; Ciprofloxacin; Pharmaceuticals; Wastewater treatment
资金
- Ataturk University
- University of Tabriz
- Near East University
- Ataturk University Scientific Research Council [2016/169]
In this study, the heterogeneous Fenton oxidation of ciprofloxacin (CIP) in an aqueous solution was examined over the nano-sized magnetite (Fe3O4) as a catalyst supplied through high-energy planetary ball milling process. To characterize the magnetite samples after and before ball milling operation, the Xray diffraction (XRD), High-resolution scanning electron microscopy (HR-SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET) and Fourier transform infrared spectroscopy (FTIR) analysis were applied. The catalytic properties of the magnetite were considerably improved because of the enhancement in its physical properties, resulted from milling process. The findings also indicated that 6 h ball-milled magnetite demonstrated better properties for elimination of CIP of about 89% following 120 min reaction at optimal conditions of H2O2 12 mM, Fe3O4 1.75 g L-1, CIP 10 mg L-1 and pH 3.0. The effects of various operational parameters, including the initial pH of the solution, H2O2 initial concentration, catalyst dosage, milling time and OP initial concentration was investigated. Application of organic and inorganic scavengers considerably decreased the CIP removal efficiency. Correspondingly, with respect to the leached iron values at pH 3, it was concluded that CIP elimination was mainly occurred through heterogeneous Fenton procedure. This process included the adsorption and oxidation phases in which the hydroxyl radicals ((OH)-O-center dot) played a significant role. GC-MS analysis was used for recording of the generated intermediates of the CIP removal in the course of heterogeneous Fenton process. (C) 2018 Elsevier Ltd. All rights reserved.
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