期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 529, 期 -, 页码 568-574出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.06.050
关键词
Carbon dots; Molecularly imprinted polymers; Caffeic acid; Fluorescent sensor
资金
- National Natural Science Foundation of China [61775099, 21705080]
- Natural Science Foundation of Jiangsu Province [BK20171487, BK20171043]
A new and sensitive method for fluorescent determination of caffeic acid (CA) was proposed based on silane-functionazed carbon dots coated with molecularly imprinted polymers (CDs@MIPs). CDs@MIPs were prepared by using CA as the templates on the surface of silane-functionazed carbon dots(CDs) with a sol-gel process. The as-prepared CDs@MIPs were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy and fluorescence spectroscopy. The CDs@MIPs exhibited distinguished selectivity and high binding affinity to CA templates, and also showed good reusability. Under optimal conditions, the fluorescence intensity of CDs@MIPs decreased linearly with the increase of CA in the range of 0.5-200 mu M. The limit of detection was 0.11 mu M (3 sigma/K). Finally, the proposed method was successfully applied to the detection of CA in human plasma. The result indicates that the method built has promising potential for monitoring CA concentration in clinic. (C) 2018 Elsevier Inc. All rights reserved.
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