期刊
JOURNAL OF CHEMICAL THERMODYNAMICS
卷 118, 期 -, 页码 235-243出版社
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2017.11.019
关键词
Aqueous biphasic systems; Ionic liquids; Cholinium dihydrogencitrate; Non-ionic surfactants; Triton
资金
- Xunta de Galicia
- ERDF Funds [ED431F 2016/007]
- Agrupacion Europea de Cooperacion Territorial - Galicia-Norte de Portugal (GNP-AECT)
- Spanish Ministry of Economy and Competitiveness [RyC-2013-14225]
Aqueous solutions of the non-ionic surfactants Triton X-100 and Triton X-102 have been salted out with the biocompatible ionic liquid cholinium dihydrogencitrate (N1112OHDHC). The phase boundary for {Triton X-100 or Triton X-102 + N1112OHDHC + H2O} was ascertained at T = ( 293.15, 303.15, 313.15 and 323.15) K and 0.1 MPa. The binodal data were modelled by one polynomial and three exponential equations, and the tie-line data were suitably correlated by means of Othmer-Tobias, Bancroft and Setschenow empirical models. The experimental results allowed concluding that the increase of temperature and the hydrophobicity of the surfactant led to the shift of the binodal curve to the water vertex. (C) 2017 Elsevier Ltd.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据