期刊
JOURNAL OF CHEMICAL PHYSICS
卷 148, 期 4, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5010999
关键词
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资金
- Hunan Provincial Science and Technology Plan Project, China [2016TP1007]
- National Natural Science Foundation of China [21176266, U1664259]
- Automotive Partnership Canada grant [APCPJ417858]
In this study, a refined double layer model of platinum electrodes accounting for chemisorbed oxygen species, oriented interfacial water molecules, and ion size effects in solution is presented. It results in a non-monotonic surface charging relation and a peculiar capacitance vs. potential curve with a maximum and possibly negative values in the potential regime of oxide-formation. Published by AIP Publishing.
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