4.2 Article

Densities and Viscosities for Binary Liquid Mixtures of Biodiesel+1-Pentanol, 2-Pentanol, or 2-Methyl-1-Butanol from (288.15 to 338.15) K at 0.1 MPa

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JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 63, 期 7, 页码 2438-2450

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AMER CHEMICAL SOC
DOI: 10.1021/acs.jced.7b00996

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  1. Consejo Nacional de Ciencia and Tecnologia (CONACyT) [CB-2016-285320]

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This work presents experimentally determined densities and viscosities of biodiesel blended with 1-pentanol, 2-pentanol, and 2-methyl-1-butanol between 288.15 and 338.15 K at 0.1 MPa. The densities are measured using a vibrating tube densimeter, and the kinematic viscosities, using a glass capillary viscometer. The measured density and viscosity of the pure components agree with values reported in the literature within average absolute percentage deviations of 0.04 and 0.83%, respectively. The excess molar volumes and viscosity deviations show positive and negative deviations from ideality, respectively. The Redlich-Kister equation is used to represent the composition behavior of the excess molar volumes and viscosity deviations. The experimental kinematic viscosities have a minimum value over a composition range of 50-90% alcohol by weight. The McAllister equation correlates the kinematic viscosity within an average absolute percentage deviation of 1.77%, while the Nava-Rios equation correlates the kinematic viscosity within 0.88%.

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