Modeling and Experimental Evaluation of Ni(II) and Pb(II) Sorption from Aqueous Solutions Using a Polyaniline/CoFeC6N6 Nanocomposite

Herein, a modified polyaniline nanocomposite containing CoFeC6N6 was prepared and tested for its sorption of Pb2+ and Ni2+ ions from aqueous solutions. The adsorbent was characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller and Fourier transform infrared analyses. The adsorption percentage increased with increasing CoFeC6N6 in the nano composite material. A pseudo-second-order model and Langmuir adsorption described the behavior of the material. Additionally, the adsorption capacity was increased by increasing the temperature. The prediction of concentrations was performed using a model based on pore diffusion and the implicit finite difference method. From a mass transfer standpoint, the best data set of D-e for Pb2+ (1.12 x 10(-9) m(2) s(-1)) and Ni2+ (0.98 x 10(-13) m(2) s(-1)) was determined.