期刊
JOURNAL OF CATALYSIS
卷 365, 期 -, 页码 292-302出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2018.06.025
关键词
Asymmetric oxygen vacancy; Electron transfer; Promoting mechanism; Aerobic oxidation; 5-Hydroxymethyl-2-furfural
资金
- Tianjin Municipal Natural Science Foundation [17JCYBJC22600]
- China Scholarship Council [201606200096, 201606200087]
- Fundamental Research Funds for the Central Universities
Investigation of Bi-doping effects on the catalytic performance of Pt/3DOM-Ce1-xBixO2-delta in the aerobic oxidation of 5-hydroxymethyl-2-furfural allows us to reveal the promoted catalytically active sites: the asymmetrical oxygen vacancies coordinated with one Bi and up to three Ce cations, such as Bi-square(-Ce)(3), where square represents an oxygen vacancy, which can easily gain oxygen atoms in favor of the CeO2 structure, and, when filled with oxygen, easily release oxygen anions in favor of six-coordination for Bi3+. The loss of electrons in the reduction of oxygen atoms at these sites would be replenished by electron transfer from Pt nanoparticles, eventually promoting the oxidation potential of the Pt nanoparticles. The present work points out that the promoted catalytic properties in Bi-doped CeO2 are mainly due to the asymmetric structures of the oxygen vacancies, rather than simply to the number of oxygen vacancies. The newly proposed model of asymmetrical active sites and electron transfer mechanism may shed light on the physicochemical properties of other solid solution substrate-supported metal nanoparticle catalysts. (C) 2018 Elsevier Inc. All rights reserved.
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